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This worksheet challenges students to balance ten different chemical equations, ranging from simple synthesis to complex double replacement reactions.

Worksheet containing ten unbalanced chemical equations for students to balance.

Worksheet containing ten unbalanced chemical equations for students to balance.

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Show Answer Key & Explanations Step-by-step solution for: Balancing Chemical Equations Worksheet
Here are the balanced chemical equations for each problem. I have worked through them step-by-step to ensure the number of atoms for each element is the same on both sides.

1. Iron and Sulfuric Acid
* Unbalanced: $\text{Fe} + \text{H}_2\text{SO}_4 \rightarrow \text{Fe}_2(\text{SO}_4)_3 + \text{H}_2$
* Step 1: Balance Iron (Fe). There are 2 Fe on the right, so put a 2 in front of Fe on the left.
* $2\text{Fe} + \text{H}_2\text{SO}_4 \rightarrow \text{Fe}_2(\text{SO}_4)_3 + \text{H}_2$
* Step 2: Balance Sulfate ($\text{SO}_4$). There are 3 sulfate groups on the right, so put a 3 in front of $\text{H}_2\text{SO}_4$.
* $2\text{Fe} + 3\text{H}_2\text{SO}_4 \rightarrow \text{Fe}_2(\text{SO}_4)_3 + \text{H}_2$
* Step 3: Balance Hydrogen (H). There are now $3 \times 2 = 6$ hydrogens on the left. Put a 3 in front of $\text{H}_2$ on the right.
* $2\text{Fe} + 3\text{H}_2\text{SO}_4 \rightarrow \text{Fe}_2(\text{SO}_4)_3 + 3\text{H}_2$

2. Methane Combustion
* Unbalanced: $\text{CH}_4 + \text{O}_2 \rightarrow \text{CO}_2 + \text{H}_2\text{O}$
* Step 1: Carbon (C) is already balanced (1 on each side).
* Step 2: Balance Hydrogen (H). There are 4 H on the left, so put a 2 in front of $\text{H}_2\text{O}$.
* $\text{CH}_4 + \text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O}$
* Step 3: Balance Oxygen (O). On the right, there are 2 (from $\text{CO}_2$) + 2 (from water) = 4 oxygens. Put a 2 in front of $\text{O}_2$.
* $\text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O}$

3. Silicon Tetrachloride Hydrolysis
* Unbalanced: $\text{SiCl}_4 + \text{H}_2\text{O} \rightarrow \text{SiO}_2 + \text{HCl}$
* Step 1: Silicon (Si) is balanced.
* Step 2: Balance Chlorine (Cl). There are 4 Cl on the left, so put a 4 in front of HCl.
* $\text{SiCl}_4 + \text{H}_2\text{O} \rightarrow \text{SiO}_2 + 4\text{HCl}$
* Step 3: Balance Hydrogen (H). There are 4 H on the right, so put a 2 in front of $\text{H}_2\text{O}$. This also gives us 2 Oxygens, which matches the $\text{SiO}_2$.
* $\text{SiCl}_4 + 2\text{H}_2\text{O} \rightarrow \text{SiO}_2 + 4\text{HCl}$

4. Silver Iodide and Sodium Sulfide
* Unbalanced: $\text{AgI} + \text{Na}_2\text{S} \rightarrow \text{Ag}_2\text{S} + \text{NaI}$
* Step 1: Balance Silver (Ag). There are 2 Ag on the right, so put a 2 in front of AgI.
* $2\text{AgI} + \text{Na}_2\text{S} \rightarrow \text{Ag}_2\text{S} + \text{NaI}$
* Step 2: Balance Iodine (I). There are 2 I on the left, so put a 2 in front of NaI. This also balances the Sodium (Na).
* $2\text{AgI} + \text{Na}_2\text{S} \rightarrow \text{Ag}_2\text{S} + 2\text{NaI}$

5. Ammonia Oxidation
* Unbalanced: $\text{NH}_3 + \text{O}_2 \rightarrow \text{NO} + \text{H}_2\text{O}$
* Step 1: Balance Hydrogen (H). Left has 3, Right has 2. The least common multiple is 6. Put a 2 in front of $\text{NH}_3$ and a 3 in front of $\text{H}_2\text{O}$.
* $2\text{NH}_3 + \text{O}_2 \rightarrow \text{NO} + 3\text{H}_2\text{O}$
* Step 2: Balance Nitrogen (N). Left has 2 N. Put a 2 in front of NO.
* $2\text{NH}_3 + \text{O}_2 \rightarrow 2\text{NO} + 3\text{H}_2\text{O}$
* Step 3: Balance Oxygen (O). Right has $2 + 3 = 5$ oxygens. We need 5 on the left, but $\text{O}_2$ comes in pairs. To fix this, double all coefficients from Step 2.
* $4\text{NH}_3 + \text{O}_2 \rightarrow 4\text{NO} + 6\text{H}_2\text{O}$
* Step 4: Now count Oxygen again. Right has $4 + 6 = 10$. Put a 5 in front of $\text{O}_2$.
* $4\text{NH}_3 + 5\text{O}_2 \rightarrow 4\text{NO} + 6\text{H}_2\text{O}$

6. Iron(III) Oxide Reduction
* Unbalanced: $\text{FeO}_3 + \text{CO} \rightarrow \text{Fe} + \text{CO}_2$
*(Note: Standard iron oxide is usually $\text{Fe}_2\text{O}_3$, but we will balance exactly what is written: $\text{FeO}_3$)*
* Step 1: Balance Oxygen in the iron compound. $\text{FeO}_3$ has 3 oxygens. We need 3 CO molecules to take them away and make 3 $\text{CO}_2$.
* $\text{FeO}_3 + 3\text{CO} \rightarrow \text{Fe} + 3\text{CO}_2$
* Step 2: Check Iron (Fe). 1 on left, 1 on right. It is balanced.
* $\text{FeO}_3 + 3\text{CO} \rightarrow \text{Fe} + 3\text{CO}_2$

7. Silicon Dioxide and Hydrofluoric Acid
* Unbalanced: $\text{SiO}_2 + \text{HF} \rightarrow \text{SiF}_4 + \text{H}_2\text{O}$
* Step 1: Balance Fluorine (F). There are 4 F on the right, so put a 4 in front of HF.
* $\text{SiO}_2 + 4\text{HF} \rightarrow \text{SiF}_4 + \text{H}_2\text{O}$
* Step 2: Balance Hydrogen (H). There are 4 H on the left, so put a 2 in front of $\text{H}_2\text{O}$. This also provides the 2 Oxygens needed for $\text{SiO}_2$.
* $\text{SiO}_2 + 4\text{HF} \rightarrow \text{SiF}_4 + 2\text{H}_2\text{O}$

8. Sodium Bromide and Chlorine
* Unbalanced: $\text{NaBr} + \text{Cl}_2 \rightarrow \text{NaCl} + \text{Br}_2$
* Step 1: Balance Chlorine (Cl) and Bromine (Br). Both appear as pairs on one side and singles on the other. Put a 2 in front of NaBr and a 2 in front of NaCl.
* $2\text{NaBr} + \text{Cl}_2 \rightarrow 2\text{NaCl} + \text{Br}_2$

9. Ammonium Phosphate and Lead(IV) Nitrate
* Unbalanced: $(\text{NH}_4)_3\text{PO}_4 + \text{Pb}(\text{NO}_3)_4 \rightarrow \text{Pb}_3(\text{PO}_4)_4 + \text{NH}_4\text{NO}_3$
* Step 1: Balance Lead (Pb). There are 3 Pb on the right, so put a 3 in front of $\text{Pb}(\text{NO}_3)_4$.
* $(\text{NH}_4)_3\text{PO}_4 + 3\text{Pb}(\text{NO}_3)_4 \rightarrow \text{Pb}_3(\text{PO}_4)_4 + \text{NH}_4\text{NO}_3$
* Step 2: Balance Phosphate ($\text{PO}_4$). There are 4 $\text{PO}_4$ groups on the right, so put a 4 in front of $(\text{NH}_4)_3\text{PO}_4$.
* $4(\text{NH}_4)_3\text{PO}_4 + 3\text{Pb}(\text{NO}_3)_4 \rightarrow \text{Pb}_3(\text{PO}_4)_4 + \text{NH}_4\text{NO}_3$
* Step 3: Balance Nitrogen and Ammonium.
* Left side: $4 \times 3 = 12$ Ammoniums ($\text{NH}_4$).
* Left side: $3 \times 4 = 12$ Nitrates ($\text{NO}_3$).
* So, put a 12 in front of $\text{NH}_4\text{NO}_3$.
* $4(\text{NH}_4)_3\text{PO}_4 + 3\text{Pb}(\text{NO}_3)_4 \rightarrow \text{Pb}_3(\text{PO}_4)_4 + 12\text{NH}_4\text{NO}_3$

10. Magnesium Hydroxide and Hydrochloric Acid
* Unbalanced: $\text{Mg(OH)}_2 + \text{HCl} \rightarrow \text{MgCl}_2 + \text{H}_2\text{O}$
* Step 1: Balance Chlorine (Cl). There are 2 Cl on the right, so put a 2 in front of HCl.
* $\text{Mg(OH)}_2 + 2\text{HCl} \rightarrow \text{MgCl}_2 + \text{H}_2\text{O}$
* Step 2: Balance Hydrogen (H) and Oxygen (O).
* Left: 2 H from hydroxide + 2 H from acid = 4 H total. 2 O from hydroxide.
* Right: Need 4 H and 2 O. Put a 2 in front of $\text{H}_2\text{O}$.
* $\text{Mg(OH)}_2 + 2\text{HCl} \rightarrow \text{MgCl}_2 + 2\text{H}_2\text{O}$

Final Answer:
1. 2 Fe + 3 H₂SO₄ → 1 Fe₂(SO₄)₃ + 3 H₂
2. 1 CH₄ + 2 O₂ → 1 CO₂ + 2 H₂O
3. 1 SiCl₄ + 2 H₂O → 1 SiO₂ + 4 HCl
4. 2 AgI + 1 Na₂S → 1 Ag₂S + 2 NaI
5. 4 NH₃ + 5 O₂ → 4 NO + 6 H₂O
6. 1 FeO₃ + 3 CO → 1 Fe + 3 CO₂
7. 1 SiO₂ + 4 HF → 1 SiF₄ + 2 H₂O
8. 2 NaBr + 1 Cl₂ → 2 NaCl + 1 Br₂
9. 4 (NH₄)₃PO₄ + 3 Pb(NO₃)₄ → 1 Pb₃(PO₄)₄ + 12 NH₄NO₃
10. 1 Mg(OH)₂ + 2 HCl → 1 MgCl₂ + 2 H₂O
Parent Tip: Review the logic above to help your child master the concept of balanced and unbalanced chemical equations worksheet.
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