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Nomenclature of cycloalkenes: Rules for naming with "cyclo" prefix, "ene" suffix, and correct numbering for double bonds and substituents.

Diagram illustrating the nomenclature rules for cycloalkenes, showing how the prefix "cyclo" is added and the suffix changes from "ane" to "ene," with examples of cyclohexane and cyclohexene, and numbering rules for substituents and double bonds.

Diagram illustrating the nomenclature rules for cycloalkenes, showing how the prefix "cyclo" is added and the suffix changes from "ane" to "ene," with examples of cyclohexane and cyclohexene, and numbering rules for substituents and double bonds.

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Show Answer Key & Explanations Step-by-step solution for: Naming Alkenes - Chemistry Steps

Problem Analysis:


The image provides a guide on the nomenclature of cycloalkenes, focusing on how to name cyclic compounds with double bonds (cycloalkenes) and their substituents. The key points are:

1. Prefix "cyclo": Added to indicate the cyclic nature of the compound.
2. Suffix change: From "-ane" (for alkanes) to "-ene" (for alkenes).
3. Numbering rules:
- The double bond (`C=C`) is given the lowest possible locant.
- Substituents are numbered such that they have the lowest possible locants.
- If there is a choice between two numbering schemes, the one that gives the shortest chain for the substituent is preferred.

Task:


The task involves understanding and applying these rules to correctly name cycloalkenes with substituents.

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Solution Explanation:



#### 1. Basic Cycloalkanes vs. Cycloalkenes
- Cyclohexane: A six-membered ring without a double bond.
- Formula: \( \text{C}_6\text{H}_{12} \)
- Name: cyclohexane

- Cyclohexene: A six-membered ring with one double bond.
- Formula: \( \text{C}_6\text{H}_{10} \)
- Name: cyclohexene
- The suffix changes from "-ane" to "-ene" to indicate the presence of a double bond.

#### 2. Substituted Cycloalkenes
- Methylcyclohexane: A methyl group (\(-\text{CH}_3\)) is attached to a cyclohexane ring.
- The methyl group can be located at any carbon atom in the ring.
- Name: methylcyclohexane (no need for a number since there is only one substituent).

- 4-Methylcyclohex-1-ene: A methyl group is attached to a cyclohexene ring.
- The double bond is located between carbons 1 and 2 (lowest locant for the double bond).
- The methyl group is located on carbon 4 (second lowest locant for the substituent).
- Name: 4-methylcyclohex-1-ene

#### 3. Numbering Direction
- When naming substituted cycloalkenes, the numbering starts from the carbon atom of the double bond and proceeds in the direction that gives the substituent the lowest possible locant.
- If there is a choice between two directions, the direction that results in the shortest chain for the substituent is preferred.

- Example:
- In the molecule shown, the double bond is between carbons 1 and 2.
- The methyl group can be on either carbon 4 or carbon 5.
- Numbering starting from carbon 1 and going clockwise gives the methyl group as 4-methyl.
- Numbering starting from carbon 1 and going counterclockwise gives the methyl group as 5-methyl.
- Since "4-methyl" is lower than "5-methyl," the correct name is 4-methylcyclohex-1-ene.

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Final Answer:


The correct name for the substituted cycloalkene is:
\[
\boxed{4\text{-methylcyclohex-1-ene}}
\]
Parent Tip: Review the logic above to help your child master the concept of naming alkenes worksheet.
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