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Redox chemistry worksheet with problems on oxidation states and electron transfer.

Chapter 20 Worksheet on Redox reactions, including questions on identifying oxidized and reduced substances, oxidizing and reducing agents, oxidation numbers, and electron transfer in chemical reactions.

Chapter 20 Worksheet on Redox reactions, including questions on identifying oxidized and reduced substances, oxidizing and reducing agents, oxidation numbers, and electron transfer in chemical reactions.

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Show Answer Key & Explanations Step-by-step solution for: Chapter 20 Worksheet Redox
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## Problem 1–10: Determine what is oxidized and reduced; identify oxidizing and reducing agents

General Rules:


- Oxidation: Loss of electrons → increase in oxidation number.
- Reduction: Gain of electrons → decrease in oxidation number.
- Oxidizing agent: Causes oxidation → gets reduced.
- Reducing agent: Causes reduction → gets oxidized.

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1. 2Sr + O₂ → 2SrO


- Sr: 0 → +2 (oxidized)
- O: 0 → -2 (reduced)
Oxidized: Sr
Reduced: O₂
Oxidizing agent: O₂
Reducing agent: Sr

---

2. 2Li + S → Li₂S


- Li: 0 → +1 (oxidized)
- S: 0 → -2 (reduced)
Oxidized: Li
Reduced: S
Oxidizing agent: S
Reducing agent: Li

---

3. 2Cs + Br₂ → 2CsBr


- Cs: 0 → +1 (oxidized)
- Br: 0 → -1 (reduced)
Oxidized: Cs
Reduced: Br₂
Oxidizing agent: Br₂
Reducing agent: Cs

---

4. 3Mg + N₂ → Mg₃N₂


- Mg: 0 → +2 (oxidized)
- N: 0 → -3 (reduced)
Oxidized: Mg
Reduced: N₂
Oxidizing agent: N₂
Reducing agent: Mg

---

5. 4Fe + 3O₂ → 2Fe₂O₃


- Fe: 0 → +3 (oxidized)
- O: 0 → -2 (reduced)
Oxidized: Fe
Reduced: O₂
Oxidizing agent: O₂
Reducing agent: Fe

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6. Cl₂ + 2NaBr → 2NaCl + Br₂


- Cl: 0 → -1 (reduced)
- Br: -1 → 0 (oxidized)
Oxidized: Br⁻ (in NaBr)
Reduced: Cl₂
Oxidizing agent: Cl₂
Reducing agent: NaBr (specifically Br⁻)

---

7. Si + 2F₂ → SiF₄


- Si: 0 → +4 (oxidized)
- F: 0 → -1 (reduced)
Oxidized: Si
Reduced: F₂
Oxidizing agent: F₂
Reducing agent: Si

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8. 2Ca + O₂ → 2CaO


- Ca: 0 → +2 (oxidized)
- O: 0 → -2 (reduced)
Oxidized: Ca
Reduced: O₂
Oxidizing agent: O₂
Reducing agent: Ca

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9. Mg + 2HCl → MgCl₂ + H₂


- Mg: 0 → +2 (oxidized)
- H: +1 → 0 (reduced)
Oxidized: Mg
Reduced: H⁺ (in HCl)
Oxidizing agent: HCl
Reducing agent: Mg

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10. 2Na + 2H₂O → 2NaOH + H₂


- Na: 0 → +1 (oxidized)
- H: +1 → 0 (reduced)
Oxidized: Na
Reduced: H⁺ (in H₂O)
Oxidizing agent: H₂O
Reducing agent: Na

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## Problem 11: Give the oxidation number of each kind of atom or ion

a. sulfate (SO₄²⁻):
→ O = -2 (each), total for O = -8. Charge = -2 → S + (-8) = -2 → S = +6

b. Sn (elemental tin) → 0

c. S²⁻-2

d. Fe³⁺+3

e. Sn⁴⁺+4

f. nitrate (NO₃⁻):
→ O = -2 × 3 = -6. Total charge = -1 → N + (-6) = -1 → N = +5

g. ammonium (NH₄⁺):
→ H = +1 × 4 = +4. Total charge = +1 → N + 4 = +1 → N = -3

Answers:
a. S = +6
b. Sn = 0
c. S²⁻ = -2
d. Fe³⁺ = +3
e. Sn⁴⁺ = +4
f. N = +5
g. N = -3

---

## Problem 12: Calculate oxidation number of chromium

a. Cr₂O₃
→ O = -2 × 3 = -6. Total = 0 → 2Cr = +6 → Cr = +3

b. Na₂Cr₂O₇
→ Na = +1 × 2 = +2; O = -2 × 7 = -14. Total = 0 → 2Cr + 2 -14 = 0 → 2Cr = +12 → Cr = +6

c. CrSO₄
→ SO₄²⁻ = -2 → Cr must be +2

d. chromate (CrO₄²⁻)
→ O = -2 × 4 = -8. Charge = -2 → Cr + (-8) = -2 → Cr = +6

e. dichromate (Cr₂O₇²⁻)
→ O = -2 × 7 = -14. Charge = -2 → 2Cr + (-14) = -2 → 2Cr = +12 → Cr = +6

Answers:
a. +3
b. +6
c. +2
d. +6
e. +6

---

## Problem 13: Use oxidation numbers to determine which elements are oxidized and reduced

*(Note: Not necessary to balance equations)*

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a. C + H₂SO₄ → CO₂ + SO₂ + H₂O


Assign oxidation numbers:

- C: 0 → +4 (in CO₂) → oxidized
- S: +6 (in H₂SO₄) → +4 (in SO₂) → reduced

Oxidized: C
Reduced: S

---

b. HNO₃ + HI → NO + I₂ + H₂O


- I: -1 (in HI) → 0 (in I₂) → oxidized
- N: +5 (in HNO₃) → +2 (in NO) → reduced

Oxidized: I
Reduced: N

---

c. KMnO₄ + HCl → MnCl₂ + Cl₂ + H₂O + KCl


- Mn: +7 (in KMnO₄) → +2 (in MnCl₂) → reduced
- Cl: -1 (in HCl) → 0 (in Cl₂) → oxidized

Oxidized: Cl
Reduced: Mn

---

d. Sb + HNO₃ → Sb₂O₅ + NO + H₂O


- Sb: 0 → +5 (in Sb₂O₅) → oxidized
- N: +5 (in HNO₃) → +2 (in NO) → reduced

Oxidized: Sb
Reduced: N

---

## Problem 14: For each reaction in Problem 13, identify oxidizing and reducing agents

Recall:
- Oxidizing agent → gets reduced
- Reducing agent → gets oxidized

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a. C + H₂SO₄ → ...


- Reduced: S → in H₂SO₄ → oxidizing agent: H₂SO₄
- Oxidized: C → reducing agent: C

Oxidizing agent: H₂SO₄
Reducing agent: C

---

b. HNO₃ + HI → ...


- Reduced: N → in HNO₃ → oxidizing agent: HNO₃
- Oxidized: I → in HI → reducing agent: HI

Oxidizing agent: HNO₃
Reducing agent: HI

---

c. KMnO₄ + HCl → ...


- Reduced: Mn → in KMnO₄ → oxidizing agent: KMnO₄
- Oxidized: Cl → in HCl → reducing agent: HCl

Oxidizing agent: KMnO₄
Reducing agent: HCl

---

d. Sb + HNO₃ → ...


- Reduced: N → in HNO₃ → oxidizing agent: HNO₃
- Oxidized: Sb → reducing agent: Sb

Oxidizing agent: HNO₃
Reducing agent: Sb

---

## Final Summary:

All problems solved with clear explanations using oxidation number changes.

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