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Chemistry worksheet on percent yield with detailed solutions for four different chemical reactions.

Chemistry worksheet with four percent yield problems and solutions, including calculations for reactions involving calcium oxide, aluminum, zinc sulfide, and nitrogen.

Chemistry worksheet with four percent yield problems and solutions, including calculations for reactions involving calcium oxide, aluminum, zinc sulfide, and nitrogen.

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Show Answer Key & Explanations Step-by-step solution for: Percent Yield | Lecture notes Chemistry | Docsity
The image you've uploaded contains a chemistry worksheet on percent yield, along with the key (solutions) for four problems. Below is a detailed explanation of each problem and its solution, as shown in the key.

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🔬 Chemistry: Percent Yield



Percent yield is calculated using the formula:

$$
\text{Percent Yield} = \left( \frac{\text{Actual Yield}}{\text{Theoretical Yield}} \right) \times 100\%
$$

We use stoichiometry to find the theoretical yield based on the balanced chemical equation, then compare it to the actual yield from the experiment.

---

## Problem 1: Slaked Lime Production

Reaction:
$$
\text{CaO} + \text{H}_2\text{O} \rightarrow \text{Ca(OH)}_2
$$

- Start with: 2400 g CaO
- Actual yield of Ca(OH)₂: 2060 g
- Water is in excess → CaO is the limiting reactant

Step-by-step Solution:



1. Find moles of CaO:
$$
\frac{2400\ \text{g CaO}}{56\ \text{g/mol}} = 42.857\ \text{mol CaO}
$$

2. Use stoichiometry to find theoretical yield of Ca(OH)₂:
- 1 mol CaO → 1 mol Ca(OH)₂
- So, 42.857 mol CaO → 42.857 mol Ca(OH)₂

3. Convert to grams:
$$
42.857\ \text{mol} \times 74\ \text{g/mol} = 3171\ \text{g Ca(OH)}_2
$$

4. Calculate percent yield:
$$
\% \text{Yield} = \left( \frac{2060}{3171} \right) \times 100\% = 65\%
$$

Answer: 65%

---

## Problem 2: Thermite Reaction

Reaction:
$$
\text{Fe}_2\text{O}_3 + 2\text{Al} \rightarrow \text{Al}_2\text{O}_3 + 2\text{Fe}
$$

- Aluminum mass: 258 g
- Rust (Fe₂O₃) is in excess → Al is limiting reactant
- Actual yield of Fe: 464 g

Step-by-step Solution:



1. Moles of Al:
$$
\frac{258\ \text{g}}{27\ \text{g/mol}} = 9.556\ \text{mol Al}
$$

2. Stoichiometry:
- 2 mol Al → 2 mol Fe → 1:1 ratio
- So, 9.556 mol Al → 9.556 mol Fe

3. Mass of Fe (theoretical):
$$
9.556\ \text{mol} \times 55.8\ \text{g/mol} = 533\ \text{g Fe}
$$

4. Percent yield:
$$
\left( \frac{464}{533} \right) \times 100\% = 87\%
$$

Answer: 87%

---

## Problem 3: Sulfur Dioxide from Zinc Sulfide

Reaction:
$$
2\text{ZnS} + 3\text{O}_2 \rightarrow 2\text{ZnO} + 2\text{SO}_2
$$

- Molecules of ZnS: $1.5 \times 10^{27}$
- Oxygen is in excess → ZnS is limiting
- Percent yield = 75%
- Find actual volume of SO₂ at STP

Step-by-step Solution:



1. Convert molecules to moles:
$$
\frac{1.5 \times 10^{27}\ \text{molecules}}{6.02 \times 10^{23}\ \text{molecules/mol}} = 2.49 \times 10^3\ \text{mol ZnS}
$$

2. Stoichiometry:
- 2 mol ZnS → 2 mol SO₂ → 1:1 ratio
- So, $2.49 \times 10^3$ mol ZnS → $2.49 \times 10^3$ mol SO₂

3. Volume at STP (1 mol = 22.4 L):
$$
2.49 \times 10^3\ \text{mol} \times 22.4\ \text{L/mol} = 5.58 \times 10^4\ \text{L SO}_2
$$

→ This is the theoretical yield.

4. Actual yield (75% of theoretical):
$$
0.75 \times 5.58 \times 10^4 = 4.19 \times 10^4\ \text{L SO}_2
$$

Answer: $4.19 \times 10^4\ \text{L SO}_2$

---

## Problem 4: Haber Process

Reaction:
$$
\text{N}_2 + 3\text{H}_2 \rightarrow 2\text{NH}_3
$$

- Desired actual yield of NH₃: 700 g
- Percent yield: 70%
- Hydrogen is in excess → N₂ is limiting
- Find mass of N₂ needed

Step-by-step Solution:



1. Find theoretical yield of NH₃:
$$
\text{Percent Yield} = \frac{\text{Actual}}{\text{Theoretical}} \times 100 \\
70 = \frac{700}{\text{Theoretical}} \times 100 \\
\Rightarrow \text{Theoretical} = \frac{700}{0.70} = 1000\ \text{g NH}_3
$$

2. Moles of NH₃ (theoretical):
$$
\frac{1000\ \text{g}}{17\ \text{g/mol}} = 58.82\ \text{mol NH}_3
$$

3. Stoichiometry:
- 2 mol NH₃ ← 1 mol N₂
- So, moles of N₂ needed = $ \frac{58.82}{2} = 29.41\ \text{mol N}_2 $

4. Mass of N₂:
$$
29.41\ \text{mol} \times 28\ \text{g/mol} = 824\ \text{g N}_2
$$

Answer: 824 g N₂

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📝 Final Answers Summary:



| Problem | Answer |
|--------|--------|
| 1 | 65% |
| 2 | 87% |
| 3 | $4.19 \times 10^4\ \text{L SO}_2$ |
| 4 | 824 g N₂ |

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💡 Key Concepts Recap:



- Theoretical yield: Maximum amount possible based on stoichiometry.
- Actual yield: What you actually get in the lab.
- Percent yield: Measures efficiency of reaction.
- Always identify the limiting reactant.
- Use molar masses, balanced equations, and unit conversions carefully.

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