Problem Overview:
The task involves using the
VSEPR (Valence Shell Electron Pair Repulsion) theory to determine the molecular structure of given molecules. The goal is to fill out a table that includes:
1.
Drawing the Lewis Structure of the molecule.
2.
Using the VSEPR chart to determine the electron pair geometry and molecular shape.
3.
Determining the molecular structure based on the VSEPR model.
4.
Drawing the VSEPR model of the molecule.
The first row for
H₂O is provided as a model, and we need to complete the second row for
SiH₄.
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Step-by-Step Solution:
####
1. H₂O (Water)
The first row is already filled out as a model. Let's review it briefly:
-
Lewis Structure:
- Central atom: Oxygen (O)
- Bonded atoms: 2 Hydrogen (H) atoms
- Lone pairs: 2 lone pairs on the oxygen atom
- Total domains: 4 (2 bonds + 2 lone pairs)
-
VSEPR Chart:
- Total domains: 4
- Shape: Tetrahedral (electron pair geometry)
- Geometry: Bent (molecular shape due to lone pairs)
-
Molecular Structure:
- The bent shape arises because the lone pairs repel the bonding pairs more strongly than bonding pairs repel each other.
-
VSEPR Model:
- A visual representation showing the tetrahedral arrangement of electron domains with the lone pairs causing the bent shape.
####
2. SiH₄ (Silane)
Now, let’s analyze
SiH₄ step by step:
#####
a. Draw the Lewis Structure
-
Central Atom: Silicon (Si)
-
Bonded Atoms: 4 Hydrogen (H) atoms
-
Lone Pairs: 0 lone pairs on the silicon atom (since all valence electrons are used in bonding)
-
Total Domains: 4 (4 single bonds)
#####
b. Use the VSEPR Chart
-
Total Domains: 4
-
Shape: Tetrahedral (both electron pair geometry and molecular geometry, as there are no lone pairs)
#####
c. Determine the Molecular Structure
- Since there are no lone pairs, the molecular geometry matches the electron pair geometry.
- The molecule is
tetrahedral.
#####
d. Draw the VSEPR Model
- A visual representation showing the tetrahedral arrangement of the four hydrogen atoms around the central silicon atom.
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Filling Out the Table for SiH₄
| Component | Draw the Lewis Structure | Use the VSEPR Chart to Determine the Structure of the Molecule | Draw the VSEPR Model |
|-----------|--------------------------|-------------------------------------------------------------|-----------------------|
| SiH₄ | <img src="lewis_structure_sih4.png" alt="Lewis Structure of SiH₄"> | Total Domains: 4<br>Bonded Atoms: 4<br>Lone Pairs: 0<br>Geometry: Tetrahedral | <img src="vsepr_model_sih4.png" alt="VSEPR Model of SiH₄"> |
---
Explanation of the Solution:
1.
Lewis Structure:
- For
SiH₄, the central silicon atom forms 4 single bonds with 4 hydrogen atoms. There are no lone pairs on the silicon atom.
2.
VSEPR Chart:
- With 4 total domains (all bonded), the electron pair geometry is tetrahedral.
- Since there are no lone pairs, the molecular geometry is also tetrahedral.
3.
Molecular Structure:
- The absence of lone pairs means that the repulsion is symmetric, resulting in a perfect tetrahedral shape.
4.
VSEPR Model:
- The model shows the three-dimensional arrangement of the atoms, confirming the tetrahedral geometry.
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Final Answer:
\boxed{
\text{See the completed table above for SiH₄.}
}
Parent Tip: Review the logic above to help your child master the concept of molecular structure worksheet.