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Example 1: Name the ionic compound Fe(OH)₃ using the table of common polyatomic ions.

Example 1 showing the ionic compound Fe(OH)₃ and a table of common polyatomic ions including NH₄⁺, NO₂⁻, NO₃⁻, OH⁻, SO₃²⁻, SO₄²⁻, PO₄³⁻, and CO₃²⁻ with their names.

Example 1 showing the ionic compound Fe(OH)₃ and a table of common polyatomic ions including NH₄⁺, NO₂⁻, NO₃⁻, OH⁻, SO₃²⁻, SO₄²⁻, PO₄³⁻, and CO₃²⁻ with their names.

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Show Answer Key & Explanations Step-by-step solution for: Naming Ionic Compounds that have Polyatomic Ions | Chemistry ...
Let's solve the problem step by step.

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Problem:


Write the name of the ionic compound:
Fe(OH)₃

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Step 1: Identify the ions present



The compound Fe(OH)₃ consists of:

- Fe: Iron (a transition metal)
- (OH)₃: Three hydroxide ions

From the table provided:
- OH⁻ is the hydroxide ion (a polyatomic ion with a -1 charge)

So, each OH⁻ has a -1 charge.
Since there are three OH⁻ ions:
Total negative charge = 3 × (-1) = -3

To balance this, the iron ion must have a +3 charge to make the compound neutral.

Therefore, the iron ion is Fe³⁺.

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Step 2: Determine the name of the cation



Iron (Fe) is a transition metal, which means it can form more than one type of ion (variable oxidation states). So we must specify its charge using Roman numerals in parentheses.

Since Fe is +3, we write iron(III).

> Note: The Roman numeral indicates the charge of the metal ion.

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Step 3: Name the anion



The anion is OH⁻, which is called hydroxide.

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Step 4: Combine the names



Now, combine the cation and anion names:

- Cation: Iron(III)
- Anion: Hydroxide

So, the full name is:

> Iron(III) hydroxide

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Final Answer:


Iron(III) hydroxide

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🔍 Explanation Summary:


- The formula Fe(OH)₃ shows three hydroxide ions (each -1), so total charge = -3.
- Therefore, Fe must be +3 → Fe³⁺.
- Since iron is a transition metal, we use Roman numerals to indicate its charge.
- The name includes the metal name followed by the charge in parentheses, then the anion name.

This naming follows IUPAC rules for ionic compounds with variable-charge metals.
Parent Tip: Review the logic above to help your child master the concept of naming polyatomic ions worksheet.
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