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Structural formulas of ten organic compounds with different functional groups.

A diagram showing ten different organic molecules labeled a through j, each with various functional groups such as carboxylic acids, alcohols, nitriles, halides, and amines, displayed in a two-column format.

A diagram showing ten different organic molecules labeled a through j, each with various functional groups such as carboxylic acids, alcohols, nitriles, halides, and amines, displayed in a two-column format.

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Show Answer Key & Explanations Step-by-step solution for: Naming Carboxylic Acid Derivatives - Practice Problems - Chemistry ...

Problem Analysis


The task appears to involve identifying and analyzing the structures of various organic compounds. Each compound is labeled from (a) to (j), and the goal is likely to classify or describe these compounds based on their functional groups, structural features, or chemical properties.

Solution Approach


To solve this problem, we will:
1. Identify the functional groups in each compound.
2. Classify the compounds based on their structural features.
3. Provide a brief description of each compound.

Detailed Analysis of Each Compound



#### (a)
- Structure:
\[
\text{Cl-CH(CH}_3\text{)-CH}_2\text{-COOH}
\]
- Functional Groups: Chlorine atom (Cl), carboxylic acid group (–COOH).
- Classification: α-Halo acid.
- Description: This is a chlorinated carboxylic acid with a chlorine atom attached to the carbon adjacent to the carboxylic acid group.

#### (b)
- Structure:
\[
\text{CH}_3\text{-CH(CN)-CH}_2\text{-COOEt}
\]
- Functional Groups: Nitrile group (–CN), ester group (–COOEt).
- Classification: Ester with a nitrile substituent.
- Description: An ester derived from a carboxylic acid and ethanol, where the carboxylic acid has a nitrile group as a substituent.

#### (c)
- Structure:
\[
\text{HO-CH}_2\text{-CH}_2\text{-CH(CN)-CH}_3
\]
- Functional Groups: Hydroxyl group (–OH), nitrile group (–CN).
- Classification: Alcohol with a nitrile substituent.
- Description: A primary alcohol where the hydroxyl group is attached to a carbon chain that also contains a nitrile group.

#### (d)
- Structure:
\[
\text{CH}_3\text{-CH(Br)-CH}_2\text{-CONHMe}
\]
- Functional Groups: Bromine atom (Br), amide group (–CONH–).
- Classification: α-Halo amide.
- Description: An amide where the nitrogen is bonded to a methyl group, and the carbon adjacent to the amide group has a bromine substituent.

#### (e)
- Structure:
\[
\text{Br-CH(CH}_3\text{)-C(OH)(CH}_3\text{)-CH}_2\text{-COOH}
\]
- Functional Groups: Bromine atom (Br), carboxylic acid group (–COOH), hydroxyl group (–OH).
- Classification: α-Halo β-hydroxy acid.
- Description: A carboxylic acid with a bromine atom on the carbon adjacent to the carboxylic acid group and a hydroxyl group on the next carbon.

#### (f)
- Structure:
\[
\text{CH}_3\text{-CH(CH}_3\text{)-CH(CH}_3\text{)-CH}_2\text{-COOH}
\]
- Functional Groups: Carboxylic acid group (–COOH).
- Classification: Branched-chain carboxylic acid.
- Description: A carboxylic acid with a branched alkyl chain.

#### (g)
- Structure:
\[
\text{CH}_3\text{-CH=CH-CH(CN)-OH}
\]
- Functional Groups: Alkene (double bond), nitrile group (–CN), hydroxyl group (–OH).
- Classification: Allylic alcohol with a nitrile substituent.
- Description: An allylic alcohol where the hydroxyl group is attached to a carbon that is part of an alkene, and the alkene has a nitrile substituent.

#### (h)
- Structure:
\[
\text{CH}_3\text{-CH(CH}_3\text{)-CH}_2\text{-COCl}
\]
- Functional Groups: Chloroformate group (–COCl).
- Classification: Acid chloride.
- Description: An acid chloride derived from a branched-chain carboxylic acid.

#### (i)
- Structure:
\[
\text{Cl-C(CH}_2\text{COOH)}_2
\]
- Functional Groups: Chlorine atom (Cl), carboxylic acid group (–COOH).
- Classification: Dicarboxylic acid with a chlorine substituent.
- Description: A dicarboxylic acid where the two carboxylic acid groups are attached to a central carbon, which also has a chlorine substituent.

#### (j)
- Structure:
\[
\text{NH}_2\text{-CH(CH}_2\text{-NH}_2\text{)-COOH}
\]
- Functional Groups: Amine groups (–NH₂), carboxylic acid group (–COOH).
- Classification: α-Amino acid.
- Description: An amino acid where the carboxylic acid group and one of the amine groups are attached to the same carbon atom, and there is an additional amine group on the adjacent carbon.

Final Answer


Each compound has been analyzed based on its functional groups and structural features. The detailed descriptions provide a clear understanding of the nature of each molecule.

\[
\boxed{
\begin{array}{l}
\text{(a) α-Halo acid} \\
\text{(b) Ester with a nitrile substituent} \\
\text{(c) Alcohol with a nitrile substituent} \\
\text{(d) α-Halo amide} \\
\text{(e) α-Halo β-hydroxy acid} \\
\text{(f) Branched-chain carboxylic acid} \\
\text{(g) Allylic alcohol with a nitrile substituent} \\
\text{(h) Acid chloride} \\
\text{(i) Dicarboxylic acid with a chlorine substituent} \\
\text{(j) α-Amino acid}
\end{array}
}
\]
Parent Tip: Review the logic above to help your child master the concept of organic chemistry nomenclature practice worksheet.
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